If it's a "normal" recent Marshall cab, it will have the connection panel that allows you some configs.

It allows for the following configurations:
1x16 Ohm, Mono
1x4 Ohm, Mono
2x8 Ohm, Stereo
You should set the switch to Mono and use 16 Ohm on the amp and the Cab, 16 Ohm always sounds best to me. Try the 4 Ohm Tap to compare, by matching the amp 4 Ohm out to the right input in Mono, maybe you like that better. Alternatively, if you connect the 8 Ohm speaker out to the cab set to stereo, you should be only using two of the 4 speakers in 8 Ohm, which could be a viable way to get volume down a bit.
In doubt, I would always measure resistance with a multimeter. A cab that is 8 Ohm will read about 5 Ohm on a MM, a Cab with 16 Ohm will read about 13 Ohm. Don't ask me why, has to do with reactive resistance or something, but like this you can always ensure everything is wired correctly.