Both guitars are pretty good and it really depends on personal taste. As some have mentioned, the LTD might have been more expensive, but personally I think they both have a comparable value overall.
Some of the differences would be
- classic/cool vibe & iconic body shape (V)
- extra jumbo frets (LTD), 24 frets
- pickups
I think it is a really tough choice. I already have an Eclipse (although an ESP one with less "bling") and I like it a lot, primarily because of its tuning stability and playability. I've also always wanted a V because it is just such a cool and iconic looking guitar!