Please also make sure you know how to drain the caps before sticking any fingers inside the amp.
I've never opened up an amp before so not sure how to do this. What is the best way?
With your particular amp, you can get the caps mostly discharged before even opening the chassis. Just play the amp, then unplug the amp from the wall, leaving the power and standby switches both on "ON".
Straight away, play some loud chords on your guitar and you will hear the notes playing, then getting quieter and quieter. What you are hearing is the caps discharging their stored energy, until they are only holding about 20V, which will not give you much of a shock at all, if any.
The amp should now basically be fairly safe to open up. Still be fairly careful not to touch anything inside the chassis until you have checked the caps with a voltmeter !
Once you have the chassis open, use a voltmeter to check the voltages of each of the big electrolytic can caps. The voltages to be checked are between the + terminal of each cap, and the amp chassis. Each one should show about 20-30ish volts at this point. Finish discharging the caps by shorting each cap to the chassis using a wire that is touched on the chassis and the other on the + terminal of the cap. The wire should obviously be insulated and you hold the insulated bit ! The voltages at this point should be very minimal, but it's best to be over-careful.
If you had not already mostly discharged the caps by playing the amp straight after the amp was switched off, then you should not use a simple lead to discharge the caps safely, as you'd be looking at about 450 Volts, and sparks would fly. To discharge fully charged caps, you need to have a lead with an insulated 10K or 100K resistor in the middle of it, with insulated crocodile clips on each end. Using that, fully charged caps can be discharged to the amp's chassis safely, and in a controlled manner. Some old fashioned techs still tell stories of merely using a big screwdriver to discharge caps, but I would not advise it !
Then you check the voltages again with a voltmeter, and only then should you be ready to start soldering !! (oh, and watch the end of that soldering iron - they get hot, I believe !).