Back in the day much equipment that used valves was left on permanently (broadcast, radar, studio etc). Many hi-fi punters leave the heater of valves in their amps permanently on (although often at a slightly lower voltage), so that the amp reaches optimum listen temperature quicker.
Turning valves on and off will cause your valves more stress than leaving them on standby. I would also agree that in a guitar amp, which won't be left in standby for ages, cathode poising is not something I would worry about
However, as stated above the heat dissipated into the amp may be a problem depending on how the amp is built.