I read on the marshall forum i should have a fully balanced valve in the PI what exactly does this mean?
Balanced means each triode in the tube have operating characteristics as close as possible to each other
A marshall PI schematic is something similar to this.

each 12AX7, AT7, or whatever has two triodes in it, but they don't have identical operating characteristics.
for example the B side (pins 6,7,8) operates with lower noise (i think) and sligthly different levels of gain to side A (pins 1,2,3).
In that picture above, you can see the bottom of the triodes are all linked together to ground sharing the same resistors, but at the top there is an 82K and 100K resistor from B+. These values are setting the levels of gain differently in each triode in an attempt to make up for the operating differences of each triode of whatever tube you put in.
I think in actual fact it should be 91K and 100K, to be more balanced. A lot of people now use 100k and 100k but 82k/100k is the typical marshall arrangement.
i don't think having a balanced PI matters too much in a marshall. an imbalance in the PI can also create desirable(?) distortion in the power stage. As long its not totally imbalanced i guess. It's down to what your ears like.
certain amps have a pot to perfectly balance any tube, like the symmetry pot in the Ubershall.
I don't think balanced PI's matters when it comes to certain amps like some Orange amps, vox night train or the Peavey Valveking, which use a different type of PI (cathodyne)