I've had issues soldering wires to the back of pots simply because you do need a great deal of heat and because there's no physical connection to hold the wire in place while doing the work. At the same time, I've never had a problem soldering the lug that needs grounding to the pot, so I've recently been soldering the ground wire to the lug while soldering the lug to the pot. Just bend the wire around the lug and get a strong physical connection, bend the lug towards the pot, and stick the iron between the lug and pot. The solder flows to everything and I get a nice, strong and shiny connection. Plus, you've only heated the pot once, so you're much less likely to ruin anything.
There could be some downside that I'm not anticipating, such as the relative difficulty of "undoing" this solder joint should you want to change your wiring type, but I've never had a grounding issue on any guitar where I've used this technique.