As usual with guitar players, the Peter Green out of phase thing has given rise to much discussion and a fair number of myths and legends. Should you reverse the magnet? Reverse the winding of the coils? Turn your neck pickup round so the screw polepieces face the bridge (which doesn't actually affect the phase relationship at all...)?
Bottom line is, simplest way to do it, if you have a regular set of BKP humbuckers with 4-conductor wiring:
Swap around the connections of the red and black wires, on one of the pickups only. Everything else stays as it is.
It works best if the two pickups are fairly well-matched in output, and if you have two volume controls, you'll find you can vary the out-of-phase effect by balancing the volume of the pickups.